Which set of elements has a strong tendency to form cations? Or which of the elements are the most electropositive elements?

The elements belonging to Group 1 and group 2 of periodic table has the strong tendency to form cations. The reason behind this tendency is that the elements belonging to group 1 and 2 have one and two valance electrons respectively. By loosing the valence electrons, they will aquire noble gas configuration. It is easy to release 1 and 2 […]

Aldol Condensation

Ald + ol Ald- Aldehyde ; ol – Alcohol. As the name suggests , this is a type of reaction which involve the formation of such a molecule which have “alcohol and aldehyde” functional groups.

Perkin reaction

Perkin reaction This reaction is used in the synthesis of β-aryl-acrylic acid. This reaction is mostly used for the prepration of cinnamic acid. Coumerin, a flavouring agent is also prepared by this method.

What is the inert pair effect?

This is the which arise due to the inability of inner electrons to take part in the chemical reactions. For example in case of group 15 we have Phosphorus, Arsenic , Tin and Bismuth. They all show the oxidation states of +3 and  +5, but as we move down the group we will see that the +3 oxidation state becomes […]

Why is breaking of C-H bond given more preference over C-C bond though the bond energy of the latter is less than the first one?

In case of hydrocarbons , the c-c bond is normally safe due to following two reasons :- Difference between the electronegativity of Carbon and Hydrogen. Due to this reason the electrons of the shared pair stays closer to the C-atom which makes it easy to break the C-H bond and release hydrogen as hydronium ion H+ . 2. The carbon […]

Types of covalent bonds

On the basis of polarity , the covalent bonds can be of two types :- 1 Nonpolar covalent bond When covalent bond is formed between two similar atoms for example between hydrogen and hydrogen H2, between oxygen oxygen O2, between chlorine chlorine Cl2  , the shared pair of electrons is attracted by both atoms  with an equal force so there […]

Characteristics of a lone pair

What are the characteristics of a lone pair? Characteristics of a lone pair Lone pair are the pair of electrons that do not take part in any chemical bond. They affect the symmetry of molecule or the shape of molecule as they interfere with the other electrons of the molecule . The electrons of lone pair repel the other bond […]

Graphite and Diamond

If diamond and graphite are made of carbon, then why do they look different, and why is diamond harder than graphite? Diamond and graphite are two allotropic forms of Carbon. […]

Banana Bonds

What is a ”three centre two electron bond”? These are the type of covalent bonds in which overlapping of orbitals of three atoms take place but sharing only two electrons. These type of bonds that are found in electron deficient molecules. for example in case of BF3 , the molecule exists as a dimer that is B2F6 . Here the […]

WHY THE IONIC REACTIONS ARE FASTER?

How are reactions related to chemical bonds? The type of bond has a great effect on the rate of reaction or speed of reaction. Here we are going to discuss why and how it happens, First of all in case of ionic compounds:- Lets take example of Sodium hydroxide and Hydrochloric acid NaOH (aq) + HCl (aq) →  NaCl + […]

Why is an ionic bond not double or triple like a covalent bond?

To understand this we have to go in depth , that how the ionic bond is formed? Ionic bond is a bond basically formed due to strong electrostatic forces of attraction which is totally different from the covalent bond. Ionic bond is formed between atoms with very different  ionisation energy and electron affinity. This situation allows one atom to transfer […]

Differences between elements, compounds, and mixtures.

In our daily life we come across different kind of particles, some look alike and some we know by common names. tody we are going to arrange almost all the particles around us. Elements :- it is the purest form of matter which has only one kind of atoms. There are 118 elements known till today. For example :- Iron, […]

Azeotropes

What are azetopes? Azeotropes are the constent boiling mixtures or solutions. it means that these mixtures can not be separated by simple distillation or boiling , because they will have the same composition of mixture even in the vapour state. for example as in case of mixture of nitric acid and water, the highest attained concentration of the nitric acid […]

Bond angles of PF3 and PCl3

In case of PF3 the size of F is small and thus it approaches near to the central atom that is P. as it approaches near to P there comes the repulsion between the bond pairs, which widens the bond angle and makes it larger than in case of PCl3. Here two types of forces are deployed Bond pair – […]

The surface tension.

At surface of a liquid will their will be no forces (forces by molecules) acting on molecules in opposite directions such that the net force between molecules (only at surface) […]

How does phosphorus form 5 covalent bonds?

The number of valence electrons in phosphorus is generally 5 and it requires 3 more electrons to complete its octet. but it has an empty d-sub shell in which its electrons can excite and increase its valency from 3 to 5. in the above picture you can easily understand in case of phosphorus , the electron from s-subshell jumps to […]

What are some of the most efficient methods of preventing rusting?

Here are the five ways:- Paint the surface of metal. Oil the surface of metal or keep it covered with grease. Electroplating it with a less reactive metal will keep it safe. Galvanisation that is covering it with Zinc metal it is also called sacrificial protection. Making it cathode, most of the underground pipes are kept safe by connecting them […]

Why does a covalent bond not form a crystal lattice?

Covalent bond and ionic bond has a very basic difference that is presence of ions or not. The ionic bonds are not limited to one ion only, actually they keep on joining again and again because they are held together by basically the electrostatic forces, due to the oppositely charged ions. lets take example of NaCl molecule. The positively charged […]

What is the reason for Zn having a lower reduction capacity than Na, Mg, and Zn?

The reduction potential of a substance depends upon the ease with which an atom can release electrons. Or can loose electrons. Here in these examples Na readily looses electron , and it is the element which easily  donates or releases electrons among all it can easily give electrons to reduce other atom. Mg comes on the second position to give […]

Is Br2 an ionic or a covalent bond?

Br2  is a homoatomic molecule, a molecule with same kind of atoms. So here the electronegativity of both the atoms is same so the shared pair is equally attracted by the two atoms. There is not a chance of transfer of electrons from one atom to another. And thus they go for sharing of electrons only to satisfy their valencies. […]

Covalent bonds versus ionic bonds.

There are two types of bonds that can be formed Either by sharing of electrons , that is covalent bond. Or 2. By transfer of electrons , that is ionic bond. Now the question is that , why to go for covalent bond? An important aspect of ionic bond is that the difference of electronegativity between the two elements must […]

What is an electrophile?

See electrophile word is made up by the joining of two words “electro+phile. Electro means the “electron “ and phile means “loving” in short the electrophile is electron loving specie or attacking reagent that attacks only on the part of molecule with high electron density. For example :- H+ , H3O+ , NH4+   and BF3 etc

How is the total valency of any compound zero?

Total valency of a compound is zero. Before starting the topic lets talk about valency. Valency  is the combining capacity of an atom or element. Now if the element is having a valency = 2, It means it can make two bonds, Now if two bonds are made,  will it have a capacity to join further? No, it can’t make […]

Why is a Cl-Cl bond stronger than an F-F bond?

This is due to the following two major reasons :- The fluorine atoms are very small in size . The florine element is having the highest electronegativity. Due to these two reasons the florine atoms are so near after the F-F bonding that the start repelling each other due to higher electron desity, which makes it easy to break the […]

Are diastereomers of optically active compounds, optically inactive?

Firstly let us discuss what are optically active compounds? These are the compounds that rotate the plane of polarized light. Now Diastereomers are basically mirror images of two optically active compounds. They rotate the plane of polarized light, either to the left side or to the right. If they are present together, they cancel the effect of each other. As […]

What is the difference between molecular mass and formula mass?

In case of ionic compounds we have crystal lattice composed of ions. And there is a never ending pattern of ions and that made it difficult to calculate the molecular mass. Thus we used a simple method by taking the ratio of the ions and then adding their masses, like in case of NaCl ; 23 of Na + 35.5 […]

What are the characteristics of pure substances in points?

Here are the characteristics of pure substances They are composed of same kind of particles. Can not be solved into its components by physical method. Have characteristic melting and boiling points. All the particles or the bulk show similar chemical and physical behavior.

What is the difference between stereoisomers, optical isomers and enantiomers?

Stereoisomers :- These are the compounds that have same molecular formula but different arrangement of atoms in the space. Optical isomers :- The compunds that have same molecular formula but they rotate the plane polarised light to the different side, right side-dextrorotatory and left levorotatory. Enantiomer :- These are the compounds that are mirror images of each other and if […]

What is a racemic mixture?

On the basis of Optical activity the compounds or isomers can be classified into two types:- Those rotate the plane polarised light towards right called the dextro rotatory compounds. Those rotate the plane polarised light towards left are called Laevo rotatory compounds. The equimolar composition of the above two isomers is called racemic mixture.

How many atoms are there in 1 gram of carbon?

For  calculation of number of atoms we have to calculate the number of moles present in 1gram carbon. Multiply the number of moles with Avogadro number. Step I  Number of moles in 1 gram of carbon = given mass / molar mass Molar mass (molecular or atomic mass expressed in grams) = 12g So the number of mole= 1/12                         […]

How many oxygen atoms are there in 90g of H2O molecule?

1 molecule of H2O has 1 atom of oxygen. Firstly we will calculate the number of atoms in 90g of H2O. we will explain it in two steps:- Step I:- No.of moles of H2O = given mass / molar mass No. of moles = 90/18 = 5 moles No. Of molecules = No. of moles x Avogadro number =5 x […]

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About Me

Hi, I’m Ankush Sharma. post graduate in chemistry and organic chemistry specialist

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