Why Alkynes are less reactive than alkenes and alkanes towards electrophilic addition reaction ?

There are two reasons for less reactivity of Alkynes towards electrophillic addition reactions:-

  • Due to greater electronegativity of sp-hybridized carbon atoms of a triple bond than sp2 -hybridized carbon atoms of a double bond, pie-electrons of alkynes are more tightly held by the carbon atoms than pie electrons of alkenes and hence are less easily available for reaction with electrophiles. As a result the reactivity decrease.
  • The pie-electron cloud of alkyne makes a cylindrical electron cloud around the triple bond . Makes the electrons more delocalized and stable. And their pie electrons are less available for an addition reaction.
Structure of ethyne

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Published by Ankush Sharma

I am M.Sc (chemistry ) from Punjabi University Patiala. I am a science teacher with expertise in chemistry, with 8 years of experience in teaching. Writing and blogging is my hobby, I write whenever I am free. I am constantly working on creating a new and easy way of learning the tough things in an effective way. I am constantly working to make authentic and reliable information to be shared with my students and widen the horizons of knowledge.

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