Give an example each of miscible liquid pairs showing positive and negative deviations from Raoult’s law. Give reasons for each such deviation.

Solution

The mixtures showing positive and negative deviations are as follows:-

  1. Mixtures showing positive deviation is mixture of ethanol and acetone.

The reason behind this is :- in this case the solute and solvent interactions are weaker than the solute-solute and solvent-solvent interactions.

  • Mixtures showing negative deviation is mixture of chloroform and acetone.

The reason behind this is :- In this case the solute and solvent interactions are stronger than that of the solute – solute interactions or the solvent – solvent interactions .

Published by Ankush Sharma

I am M.Sc (chemistry ) from Punjabi University Patiala. I am a science teacher with expertise in chemistry, with 8 years of experience in teaching. Writing and blogging is my hobby, I write whenever I am free. I am constantly working on creating a new and easy way of learning the tough things in an effective way. I am constantly working to make authentic and reliable information to be shared with my students and widen the horizons of knowledge.

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