Molality of the given solution = 0.1539m
∆Tf = 273.15 – 271 = 2.15 K
Therefore ∆Tf = Kf .m
Kf = ∆Tf / m
Kf = 2.15/0.1539
Now mass of the solute W2 = 5g
Molar mass of the solute M2 = 180g
Mass of the solution W1 = 100g
Now the mass of solvent = 95g
Using the following formula:-

=4.08 K
So the freezing point of the solution will be = 273.15 – 4.08
= 269.07 K
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